Chalcopyrite Leaching in a Dimethyl Sulfoxide Solution Containing Copper Chloride
نویسندگان
چکیده
Abstract Chalcopyrite (CuFeS 2 ) is the most refractory copper mineral when treated in conventional sulfate media leaching systems. This first study to examine use of a dimethyl sulfoxide (CH 3 SOCH , DMSO) solution containing chloride (CuCl for chalcopyrite. Leaching experiments concentrate composed mainly chalcopyrite were conducted at ambient pressure 313–413 K. The fractions Cu, Fe, S, Au, and As investigated. It was found that 90% Cu extracted h, 94% 4 h 373 K, which competitive with other processes. A DMSO CuCl could selectively dissolve valuable metals Au from chalcopyrite, but leave minerals little economic value such as pyrite (FeS residue. oxidized by cupric ion proportion stoichiometric ratio initial solution, enhanced presence oxygen below
منابع مشابه
Equilibrium Acidities in Dimethyl Sulfoxide Solution
The first acidity scale to be established in a pure solvent other than water was the result of the pioneering work of Conant, Wheland, and McEwen in ether or ben~ene .~ During the past 20 years an ion-pair acidity scale covering an "effective pKa rangefrom about 15 to 40 has been developed in cyclohexylamine (CHA),6 and similar studies in other low-dielectric-constant solvents including 1,2-dim...
متن کاملcis-Dichloridotetrakis(dimethyl sulfoxide-κO)chromium(III) chloride dimethyl sulfoxide monosolvate
The structure of the title compound, [CrCl2(C2H6OS)4]Cl·C2H6OS, consists of a Cr(III) ion coordinated by four O atoms of dimethyl sulfoxide (DMSO) ligands and two chloride ions in cis positions, forming a distorted CrCl2O4 octa-hedron. An isolated Cl(-) counter-anion and a positionally disordered DMSO mol-ecule [occupancy ratio 0.654 (4):0.346 (4)] are also present. In the structure, the comple...
متن کاملDimethyl sulfoxide, diethyl fumarate solution for high dose dosimetry
Background: Dosimetry is a fundamental part of the radiation processing industry. Aqueous inorganic dosimeters have been used for gamma radiation dosimetry such as standard ferrous sulfate dosimeter. The purpose of this study was to investigate the effect of gamma radiation on the diethyl fumarate DEF in dimethyl sulfoxide DMSO solution and its possible use in chemical dosimetry. Materials and ...
متن کاملVibrational spectroscopic force field studies of dimethyl sulfoxide and hexakis(dimethyl sulfoxide)scandium(III) iodide, and crystal and solution structure of the hexakis(dimethyl sulfoxide)scandium(III) ion.
Hexakis(dimethyl sulfoxide)scandium(III) iodide, [Sc(OS(CH(3))(2))(6)]I(3) contains centrosymmetric hexasolvated scandium(III) ions with an Sc-O bond distance of 2.069(3) angstroms. EXAFS spectra yield a mean Sc-O bond distance of 2.09(1) angstroms for solvated scandium(III) ions in dimethyl sulfoxide solution, consistent with six-coordination. Raman and infrared absorption spectra have been re...
متن کاملThe Influence of Mechanical Activation of Chalcopyrite on the Selective Leaching of Copper by Sulphuric Acid
Base metal sulphides are an important source of various metals. They are typically intergrowth and due to the complex nature of their ores, the hydrometallurgical technique is the very convenient way of extracting the desired component. If it is possible to extract the metal from an ore selectively, the subsequent processing steps become less complicated. Mechanical activation seems to be a fav...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Mining, metallurgy & exploration
سال: 2021
ISSN: ['2524-3462', '2524-3470']
DOI: https://doi.org/10.1007/s42461-021-00400-3